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トリメタホスフィマト配位子を有するルテニウム、ロジウム、イリジウム錯体の構造と性質
https://doi.org/10.24789/00001219
https://doi.org/10.24789/000012192bcba7b0-4bb0-4cea-952b-ba66eae92618
名前 / ファイル | ライセンス | アクション |
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本文を見る(PDFファイル) (661.7 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-10-01 | |||||
タイトル | ||||||
タイトル | トリメタホスフィマト配位子を有するルテニウム、ロジウム、イリジウム錯体の構造と性質 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Structures and Properties of Ruthenium, Rhodium, and Iridium Complexes with a Trimetaphosphimato Ligand | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24789/00001219 | |||||
ID登録タイプ | JaLC | |||||
著者 |
上村, 聡
× 上村, 聡× 飯田, 琢也× 金尾, 啓一郎× 野川, 千種× 田邉, 資明× 大石, 克嘉× 福沢, 信一× 石井, 洋一 |
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著者別名(英) | ||||||
姓名 | KAMIMURA, Sou | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | IIDA, Takuya | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | KANAO, Keiichiro | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | NOGAWA, Chigusa | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | TANABE, Yoshiaki | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | OH-ISHI, Katsuyoshi | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | FUKUZAWA, Shin-ichi | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | ISHII, Youichi | |||||
言語 | en | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Treatment of (PPN)3[P3(NH)3O6] (PPN = (PPh3)2N+) with [(η6-C6H6)RuCl(μ-Cl)]2 in CH2Cl2 at room temperature gives the anionic ruthenium-trimetaphosphimato complex (PPN)[(η6-C6H6)-Ru{P3(NH)3O6}] (1) in 83% yield. By similar reactions the Cp∗Rh (Cp∗ = η5-C5Me5) complex (PPN)[Cp∗Rh{P3(NH)3O6}] (3) and the Cp∗Ir complex (PPN)[Cp∗Ir{P3(NH)3O6}] (4) are synthesized from [Cp∗MCl(μ-Cl)]2 (M = Rh, Ir) in high yields. X-ray diffraction studies of 1•0.5CH2Cl2, 3•CH2Cl2 and 4•CH2Cl2 have shown that these complexes adopt a three-legged piano-stool structure in the solid state, where the three axial oxygen atoms of the trimetaphosphimato ligand occupy the fac positions. The structure of 1•0.5CH2Cl2 has been compared in detail with that of the corresponding cyclotriphosphato complex (PPN)[(η6-C6H6)Ru(P3O9)] (2). The electrochemical behavior of these complexes is also described. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 【査読有】 | |||||
書誌情報 |
中央大学理工学研究所論文集 巻 11, p. 1-10, 発行日 2006-03-31 |
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出版者 | ||||||
出版者 | 中央大学理工学研究所 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1343-0068 | |||||
権利 | ||||||
権利情報 | この資料の著作権は、資料の著作者または学校法人中央大学に帰属します。著作権法が定める私的利用・引用を超える使用を希望される場合には、掲載誌発行部局へお問い合わせください。 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |