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キラルビナフチル基を有する新規光学活性フェロセンの合成と変換反応
https://doi.org/10.24789/00001217
https://doi.org/10.24789/000012173bfed4c6-ad95-4f75-8116-bc5085ccd318
名前 / ファイル | ライセンス | アクション |
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本文を見る(PDFファイル) (408.4 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-10-01 | |||||
タイトル | ||||||
タイトル | キラルビナフチル基を有する新規光学活性フェロセンの合成と変換反応 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Synthesis and Transformation of New Optically Active Ferrocenes Having a Chiral Binaphtyl Group | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24789/00001217 | |||||
ID登録タイプ | JaLC | |||||
著者 |
山本, 真久
× 山本, 真久× 菊地, 哲× 石井, 洋一× 福沢, 信一 |
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著者別名(英) | ||||||
姓名 | YAMAMOTO, Masahisa | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | KIKUCHI, Satoshi | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | ISHII, Youichi | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | FUKUZAWA, Shin-ichi | |||||
言語 | en | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The optically active ferrocene having a chiral binaphtyl group, i.e., (S)-(2’-ferrocenoyl-[1,1’]- binaphthalene-2-yl)ferrocenylmethanone 4, was readily prepared by the Friedel-Crafts reaction of (S)-1,1’-binaphtyl dicarboxylic acid dichloride 3 with ferrocene in the presence of AlCl3. The reduction of 4 with LiAlH4 gave the corresponding (R,R)-diol 5 with high stereoselectivity together with a formation of a small amount of (S, S)-ether 6, while, the reduction with DIBAH gave the (R, S)-ether 6 predominantly. The attempt for transformation of 5 to the corresponding diamine via the diacetate 7 resulted in the production of the aminoacetate 8. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 【査読有】 | |||||
書誌情報 |
中央大学理工学研究所論文集 巻 12, p. 99-105, 発行日 2007-03-31 |
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出版者 | ||||||
出版者 | 中央大学理工学研究所 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1343-0068 | |||||
権利 | ||||||
権利情報 | この資料の著作権は、資料の著作者または学校法人中央大学に帰属します。著作権法が定める私的利用・引用を超える使用を希望される場合には、掲載誌発行部局へお問い合わせください。 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |