WEKO3
アイテム
{"_buckets": {"deposit": "5caaf470-b9b7-42de-9a43-39c4c8e02883"}, "_deposit": {"created_by": 1, "id": "3812", "owners": [1], "pid": {"revision_id": 0, "type": "depid", "value": "3812"}, "status": "published"}, "_oai": {"id": "oai:chuo-u.repo.nii.ac.jp:00003812", "sets": ["257"]}, "author_link": ["24844", "24845", "24841", "23392", "24842", "24843"], "item_10002_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2013-03-31", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "7", "bibliographicPageStart": "1", "bibliographicVolumeNumber": "18", "bibliographic_titles": [{"bibliographic_title": "中央大学理工学研究所論文集"}]}]}, "item_10002_description_19": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_10002_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "A catalytic efficiency of 1,2,3-triazol-5-ylidene (tzNHC) palladium π-allyl complexes was evaluated in α-arylation of aryl ketones with aryl chlorides. Sterically hindered 1,4-(2,6-diisopropylphenyl-1,2,3-triazol-5-ylidene) was the most suitable tzNHC, and allylic ligands did not much affect the catalytic efficiency. 1,4-(2,6-Diisopropylphenyl¬1,2,3-triazol-5-ylidene) palladium(allyl) complex C3 was able to be applied to the α-arylation with several aryl chlorides. C3 also catalyzed Mizoroki-Heck reaction of aryl bromides with n-butyl acrylate to give the corresponding cinnamic acid esters in good yields.", "subitem_description_type": "Abstract"}]}, "item_10002_full_name_32": {"attribute_name": "著者別名(英)", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "24844", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "TERASHIMA, Masahiro", "nameLang": "en"}]}, {"nameIdentifiers": [{"nameIdentifier": "24845", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "INOMATA, Sayuri", "nameLang": "en"}]}, {"nameIdentifiers": [{"nameIdentifier": "24843", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "OGATA, Kenichi", "nameLang": "en"}]}, {"nameIdentifiers": [{"nameIdentifier": "23392", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "FUKUZAWA, Shin-ichi", "nameLang": "en"}]}]}, "item_10002_identifier_registration": {"attribute_name": "ID登録", "attribute_value_mlt": [{"subitem_identifier_reg_text": "10.24789/00003802", "subitem_identifier_reg_type": "JaLC"}]}, "item_10002_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "中央大学理工学研究所"}]}, "item_10002_rights_15": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "この資料の著作権は、資料の著作者または学校法人中央大学に帰属します。著作権法が定める私的利用・引用を超える使用を希望される場合には、掲載誌発行部局へお問い合わせください。"}]}, "item_10002_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1343-0068", "subitem_source_identifier_type": "ISSN"}]}, "item_10002_version_type_20": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "寺島, 貴大"}, {"creatorName": "テラシマ, マサヒロ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "24841", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "猪俣, さゆり"}, {"creatorName": "イノマタ, サユリ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "24842", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "緒方, 賢一"}, {"creatorName": "オガタ, ケンイチ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "24843", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "福沢, 信一"}, {"creatorName": "フクザワ, シンイチ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "23392", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-04-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "1343_0068~~18~1.pdf", "filesize": [{"value": "3.4 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 3400000.0, "url": {"label": "本文を見る(PDFファイル)", "url": "https://chuo-u.repo.nii.ac.jp/record/3812/files/1343_0068~~18~1.pdf"}, "version_id": "8d4db64a-6c76-4e52-8c41-3dd706085ab4"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "1,2,3-トリアゾールイリデンカルベン パラジウム π-アリル 錯体を用いるケトンの直接的α-アリール化反応と溝呂木-Heck 反応", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "1,2,3-トリアゾールイリデンカルベン パラジウム π-アリル 錯体を用いるケトンの直接的α-アリール化反応と溝呂木-Heck 反応"}, {"subitem_title": "Direct -Arylation of Ketones and Mizoroki-Heck Reaction Catalyzed by 1,2,3-Triazolylidene Carbene Palladium - Allyl Complexes", "subitem_title_language": "en"}]}, "item_type_id": "10002", "owner": "1", "path": ["257"], "permalink_uri": "https://doi.org/10.24789/00003802", "pubdate": {"attribute_name": "公開日", "attribute_value": "2013-05-17"}, "publish_date": "2013-05-17", "publish_status": "0", "recid": "3812", "relation": {}, "relation_version_is_last": true, "title": ["1,2,3-トリアゾールイリデンカルベン パラジウム π-アリル 錯体を用いるケトンの直接的α-アリール化反応と溝呂木-Heck 反応"], "weko_shared_id": -1}
1,2,3-トリアゾールイリデンカルベン パラジウム π-アリル 錯体を用いるケトンの直接的α-アリール化反応と溝呂木-Heck 反応
https://doi.org/10.24789/00003802
https://doi.org/10.24789/00003802fd13a1df-38e3-497f-8bee-19edab883eb3
名前 / ファイル | ライセンス | アクション |
---|---|---|
本文を見る(PDFファイル) (3.4 MB)
|
|
Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2013-05-17 | |||||
タイトル | ||||||
タイトル | 1,2,3-トリアゾールイリデンカルベン パラジウム π-アリル 錯体を用いるケトンの直接的α-アリール化反応と溝呂木-Heck 反応 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Direct -Arylation of Ketones and Mizoroki-Heck Reaction Catalyzed by 1,2,3-Triazolylidene Carbene Palladium - Allyl Complexes | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24789/00003802 | |||||
ID登録タイプ | JaLC | |||||
著者 |
寺島, 貴大
× 寺島, 貴大× 猪俣, さゆり× 緒方, 賢一× 福沢, 信一 |
|||||
著者別名(英) | ||||||
姓名 | TERASHIMA, Masahiro | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | INOMATA, Sayuri | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | OGATA, Kenichi | |||||
言語 | en | |||||
著者別名(英) | ||||||
姓名 | FUKUZAWA, Shin-ichi | |||||
言語 | en | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A catalytic efficiency of 1,2,3-triazol-5-ylidene (tzNHC) palladium π-allyl complexes was evaluated in α-arylation of aryl ketones with aryl chlorides. Sterically hindered 1,4-(2,6-diisopropylphenyl-1,2,3-triazol-5-ylidene) was the most suitable tzNHC, and allylic ligands did not much affect the catalytic efficiency. 1,4-(2,6-Diisopropylphenyl¬1,2,3-triazol-5-ylidene) palladium(allyl) complex C3 was able to be applied to the α-arylation with several aryl chlorides. C3 also catalyzed Mizoroki-Heck reaction of aryl bromides with n-butyl acrylate to give the corresponding cinnamic acid esters in good yields. | |||||
書誌情報 |
中央大学理工学研究所論文集 巻 18, p. 1-7, 発行日 2013-03-31 |
|||||
出版者 | ||||||
出版者 | 中央大学理工学研究所 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1343-0068 | |||||
権利 | ||||||
権利情報 | この資料の著作権は、資料の著作者または学校法人中央大学に帰属します。著作権法が定める私的利用・引用を超える使用を希望される場合には、掲載誌発行部局へお問い合わせください。 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |