{"created":"2023-05-15T13:44:39.285314+00:00","id":1210,"links":{},"metadata":{"_buckets":{"deposit":"7153d47b-6048-4ca3-b6b5-f8c8d70875d6"},"_deposit":{"created_by":1,"id":"1210","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"1210"},"status":"published"},"_oai":{"id":"oai:chuo-u.repo.nii.ac.jp:00001210","sets":["108:110"]},"author_link":["23595","23604","23601","23602","23603","23598","23386","23374","23599","23596","23600","23597"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"29","bibliographicPageStart":"19","bibliographicVolumeNumber":"15","bibliographic_titles":[{"bibliographic_title":"中央大学理工学研究所論文集"}]}]},"item_10002_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Various fluorescent ruthenium and iridium aromatic amine complexes have been known to bind to double stranded DNA(ds-DNA) and utilization of the property for DNA-chip technology has long been attempted. Among various methods of detecting complexes bound specifically to ds-DNA, electrochemiluminescence (ECL) has attracted much attention as a technique that affords low price and high-speed detection method. In this study, we have synthesized ruthenium(II) and iridium(II) complexes of bpy (2, 2’-bipyridine), phen(1,10-phenanthroline), and ppy (2-phenylpyridine) respectively with large N-aromatic diimine intercalators and investigated the DNA binding affinity by spectroscopic methods and the ECL behaviors by DNA modified ECL electrode. The results indicated that Λ-[Ru(bpy)2(tpphz)]2+ (tpphz : tetrapyrido[3,2-a:2,3’-c:3”, 2”-h:2’’’,3’’’-j]-phenazine) has high affinity and selectivity for recognition of ds-DNA compared to the Δ-form complex and the other similar ruthenium complexes. It was also revealed that [Ir(ppy)2(tpphz)]+ recognized ds-DNA a little more efficiently than the ruthenium complexes though the affinity of the iridium complex to DNA was smaller than those of the ruthenium ones.","subitem_description_type":"Abstract"}]},"item_10002_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"【査読有】","subitem_description_type":"Other"}]},"item_10002_full_name_32":{"attribute_name":"著者別名(英)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"23600","nameIdentifierScheme":"WEKO"}],"names":[{"name":"SAKURADA, Shinichi","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23601","nameIdentifierScheme":"WEKO"}],"names":[{"name":"KIMURA, Tomoya","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23602","nameIdentifierScheme":"WEKO"}],"names":[{"name":"OGAWA, Yukari","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23603","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ARII, Hidekazu","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23604","nameIdentifierScheme":"WEKO"}],"names":[{"name":"KITAMURA, Yusuke","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23386","nameIdentifierScheme":"WEKO"}],"names":[{"name":"HAGA, Masaaki","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23374","nameIdentifierScheme":"WEKO"}],"names":[{"name":"CHIKIRA, Makoto","nameLang":"en"}]}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24789/00001200","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"中央大学理工学研究所"}]},"item_10002_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"この資料の著作権は、資料の著作者または学校法人中央大学に帰属します。著作権法が定める私的利用・引用を超える使用を希望される場合には、掲載誌発行部局へお問い合わせください。"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1343-0068","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"櫻田, 伸一"},{"creatorName":"サクラダ, シンイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"木村, 友哉"},{"creatorName":"キムラ, トモヤ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"小川, ゆかり"},{"creatorName":"オガワ, ユカリ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"有井, 秀和"},{"creatorName":"アリイ, ヒデカズ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"北村, 裕介"},{"creatorName":"キタムラ, ユウスケ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"芳賀, 正明"},{"creatorName":"ハガ, マサアキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"千喜良, 誠"},{"creatorName":"チキラ, マコト","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-04-22"}],"displaytype":"detail","filename":"1343_0068~15~~19.pdf","filesize":[{"value":"1.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文を見る(PDFファイル)","url":"https://chuo-u.repo.nii.ac.jp/record/1210/files/1343_0068~15~~19.pdf"},"version_id":"dc89cbb9-4e03-4960-8308-54e5b96d5a37"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ルテニウム(Ⅱ) およびイリジウム(Ⅲ) 錯体の電気化学発光によるDNA 二重らせんの検出","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ルテニウム(Ⅱ) およびイリジウム(Ⅲ) 錯体の電気化学発光によるDNA 二重らせんの検出"},{"subitem_title":"Detection of Double-stranded DNA by Electrochemiluminescence of Ruthenium(II) and Iridium(III) Complexes","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"1","path":["110"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-10-01"},"publish_date":"2012-10-01","publish_status":"0","recid":"1210","relation_version_is_last":true,"title":["ルテニウム(Ⅱ) およびイリジウム(Ⅲ) 錯体の電気化学発光によるDNA 二重らせんの検出"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-16T13:29:40.585231+00:00"}