@article{oai:chuo-u.repo.nii.ac.jp:00001227, author = {山本, 真久 and 菊地, 哲 and 石井, 洋一 and 福沢, 信一}, journal = {中央大学理工学研究所論文集}, month = {Mar}, note = {application/pdf, The optically active ferrocene having a chiral binaphtyl group, i.e., (S)-(2’-ferrocenoyl-[1,1’]- binaphthalene-2-yl)ferrocenylmethanone 4, was readily prepared by the Friedel-Crafts reaction of (S)-1,1’-binaphtyl dicarboxylic acid dichloride 3 with ferrocene in the presence of AlCl3. The reduction of 4 with LiAlH4 gave the corresponding (R,R)-diol 5 with high stereoselectivity together with a formation of a small amount of (S, S)-ether 6, while, the reduction with DIBAH gave the (R, S)-ether 6 predominantly. The attempt for transformation of 5 to the corresponding diamine via the diacetate 7 resulted in the production of the aminoacetate 8., 【査読有】}, pages = {99--105}, title = {キラルビナフチル基を有する新規光学活性フェロセンの合成と変換反応}, volume = {12}, year = {2007}, yomi = {ヤマモト, マサヒサ and キクチ, サトシ and イシイ, ヨウイチ and フクザワ, シンイチ} }