{"created":"2023-05-15T13:44:39.991109+00:00","id":1227,"links":{},"metadata":{"_buckets":{"deposit":"4f983cf3-55be-4940-bd68-b2a03e9519c0"},"_deposit":{"created_by":1,"id":"1227","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"1227"},"status":"published"},"_oai":{"id":"oai:chuo-u.repo.nii.ac.jp:00001227","sets":["108:113"]},"author_link":["23662","23659","23661","23392","23660","23372"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2007-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"105","bibliographicPageStart":"99","bibliographicVolumeNumber":"12","bibliographic_titles":[{"bibliographic_title":"中央大学理工学研究所論文集"}]}]},"item_10002_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The optically active ferrocene having a chiral binaphtyl group, i.e., (S)-(2’-ferrocenoyl-[1,1’]- binaphthalene-2-yl)ferrocenylmethanone 4, was readily prepared by the Friedel-Crafts reaction of (S)-1,1’-binaphtyl dicarboxylic acid dichloride 3 with ferrocene in the presence of AlCl3. The reduction of 4 with LiAlH4 gave the corresponding (R,R)-diol 5 with high stereoselectivity together with a formation of a small amount of (S, S)-ether 6, while, the reduction with DIBAH gave the (R, S)-ether 6 predominantly. The attempt for transformation of 5 to the corresponding diamine via the diacetate 7 resulted in the production of the aminoacetate 8.","subitem_description_type":"Abstract"}]},"item_10002_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"【査読有】","subitem_description_type":"Other"}]},"item_10002_full_name_32":{"attribute_name":"著者別名(英)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"23661","nameIdentifierScheme":"WEKO"}],"names":[{"name":"YAMAMOTO, Masahisa","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23662","nameIdentifierScheme":"WEKO"}],"names":[{"name":"KIKUCHI, Satoshi","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23372","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ISHII, Youichi","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23392","nameIdentifierScheme":"WEKO"}],"names":[{"name":"FUKUZAWA, Shin-ichi","nameLang":"en"}]}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24789/00001217","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"中央大学理工学研究所"}]},"item_10002_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"この資料の著作権は、資料の著作者または学校法人中央大学に帰属します。著作権法が定める私的利用・引用を超える使用を希望される場合には、掲載誌発行部局へお問い合わせください。"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1343-0068","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"山本, 真久"},{"creatorName":"ヤマモト, マサヒサ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"菊地, 哲"},{"creatorName":"キクチ, サトシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"石井, 洋一"},{"creatorName":"イシイ, ヨウイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"福沢, 信一"},{"creatorName":"フクザワ, シンイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-04-22"}],"displaytype":"detail","filename":"1343_0068~12~~99.pdf","filesize":[{"value":"408.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文を見る(PDFファイル)","url":"https://chuo-u.repo.nii.ac.jp/record/1227/files/1343_0068~12~~99.pdf"},"version_id":"38f2b7d8-0623-41e3-8835-85d695f140f5"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"キラルビナフチル基を有する新規光学活性フェロセンの合成と変換反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"キラルビナフチル基を有する新規光学活性フェロセンの合成と変換反応"},{"subitem_title":"Synthesis and Transformation of New Optically Active Ferrocenes Having a Chiral Binaphtyl Group","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"1","path":["113"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-10-01"},"publish_date":"2012-10-01","publish_status":"0","recid":"1227","relation_version_is_last":true,"title":["キラルビナフチル基を有する新規光学活性フェロセンの合成と変換反応"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-16T13:29:05.686465+00:00"}