{"created":"2023-05-15T13:44:40.903263+00:00","id":1249,"links":{},"metadata":{"_buckets":{"deposit":"3ef255e6-f0e9-4e8c-af7d-68a3c9d162c6"},"_deposit":{"created_by":1,"id":"1249","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"1249"},"status":"published"},"_oai":{"id":"oai:chuo-u.repo.nii.ac.jp:00001249","sets":["108:116"]},"author_link":["23737","23738","23395","23392","23372"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"50","bibliographicPageStart":"43","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"中央大学理工学研究所論文集"}]}]},"item_10002_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The cyclotriphosphate ion as a　nBu4N salt reacts with[Cp*TaCl4](Cp*= η5-C5Me5) in CH2Cl2 at room temperature to give the anionic cyclotriphosphato complex (nBu4N)[Cp*TaCl(OH)(P3O9)](1) in 24% yield. The analogous niobium complex (PPN)[Cp*NbCl(OH)(P3O9)] (2) is synthesized by the reaction of PPN cyclotriphosphate (PPN=(PPh3)2N+) with [Cp*NbCl4] under similar conditions (42% yield). X-ray diffraction studies of 1-0.5Et2O and 2-CH2Cl2 have shown that these complexes adopt a distorted octahedral structure in the solid state, where the three axial oxygen atoms of the cyclotriphosphato ligand occupy the fac positions, and the Cl, OH, and Cp* ligands are located at the other coordination sites. The M-OH bond distances (M=Ta, 1.873(5)A;M=Nb,1.963(3)A) suggest that the Ta-OH bond has a considerable double-bond character, while the π-donation from the OH ligand to the niobium center is weak. The complex anion in 1-0.5Et2O forms a hydrogen-bonded dimeric structure. On the other hand, the complex anion in 2-CH2Cl2 is engaged in relatively strong CH…O hydrogen bonds with CH2Cl2 molecules.","subitem_description_type":"Abstract"}]},"item_10002_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"【査読有】","subitem_description_type":"Other"}]},"item_10002_full_name_32":{"attribute_name":"著者別名(英)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"23738","nameIdentifierScheme":"WEKO"}],"names":[{"name":"KAMIMURA, Sou","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23395","nameIdentifierScheme":"WEKO"}],"names":[{"name":"OH-ISHI, Katsuyoshi","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23392","nameIdentifierScheme":"WEKO"}],"names":[{"name":"FUKUZAWA, Shin-ichi","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23372","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ISHII, Youichi","nameLang":"en"}]}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24789/00001239","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"中央大学理工学研究所"}]},"item_10002_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"この資料の著作権は、資料の著作者または学校法人中央大学に帰属します。著作権法が定める私的利用・引用を超える使用を希望される場合には、掲載誌発行部局へお問い合わせください。"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1343-0068","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"上村, 聡"},{"creatorName":"カミムラ, ソウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"大石, 克嘉"},{"creatorName":"オオイシ, カツヨシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"福沢, 信一"},{"creatorName":"フクザワ, シンイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"石井, 洋一"},{"creatorName":"イシイ, ヨウイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-04-22"}],"displaytype":"detail","filename":"1343_0068~9~~43.pdf","filesize":[{"value":"148.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文を見る(PDFファイル)","url":"https://chuo-u.repo.nii.ac.jp/record/1249/files/1343_0068~9~~43.pdf"},"version_id":"ee67d69c-d7bf-43c2-befe-c17a095fe29f"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"シクロトリホスフェートを配位子とするタンタルおよびニオブ錯体の合成と構造","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"シクロトリホスフェートを配位子とするタンタルおよびニオブ錯体の合成と構造"},{"subitem_title":"Synthesis and Structures of Tantalum and Niobium Complexes with a Cyclotriphosphato Ligand","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"1","path":["116"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-10-01"},"publish_date":"2012-10-01","publish_status":"0","recid":"1249","relation_version_is_last":true,"title":["シクロトリホスフェートを配位子とするタンタルおよびニオブ錯体の合成と構造"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-16T13:28:01.775944+00:00"}