{"created":"2023-05-15T13:44:41.525625+00:00","id":1264,"links":{},"metadata":{"_buckets":{"deposit":"638d042e-e711-4174-83b2-f85477a6f12b"},"_deposit":{"created_by":1,"id":"1264","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"1264"},"status":"published"},"_oai":{"id":"oai:chuo-u.repo.nii.ac.jp:00001264","sets":["108:118"]},"author_link":["23784","23779","23782","23780","23781","23392","23783"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"43","bibliographicPageStart":"37","bibliographicVolumeNumber":"7","bibliographic_titles":[{"bibliographic_title":"中央大学理工学研究所論文集"}]}]},"item_10002_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Samarium diiodide (SmI2) in the copresence of chlorotrimethylsilane reduces cyclic ketones efficiently, compared with samarium diiodide alone, providing the corresponding reductive coupling products, alcohols, and their silyl ethers with the formation of enol silyl ethers. Possible reaction pathways for this reduction are discussed in detail. In addition, this paper also deals with the reduction of alkyl aryl ketones using a mixed system of metallic samarium and chlorotrimethylsilane, which leads to the pinacol coupling of ketones. The stereoselectivity of this coupling reaction is also investigated.","subitem_description_type":"Abstract"}]},"item_10002_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"【査読有】","subitem_description_type":"Other"}]},"item_10002_full_name_32":{"attribute_name":"著者別名(英)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"23782","nameIdentifierScheme":"WEKO"}],"names":[{"name":"OGAWA, Akiya","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23783","nameIdentifierScheme":"WEKO"}],"names":[{"name":"TANAKA, Hiromichi","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23784","nameIdentifierScheme":"WEKO"}],"names":[{"name":"AKIYAMA, Takahiko","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23392","nameIdentifierScheme":"WEKO"}],"names":[{"name":"FUKUZAWA, Shin-ichi","nameLang":"en"}]}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24789/00001254","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"中央大学理工学研究所"}]},"item_10002_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"この資料の著作権は、資料の著作者または学校法人中央大学に帰属します。著作権法が定める私的利用・引用を超える使用を希望される場合には、掲載誌発行部局へお問い合わせください。"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1343-0068","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"小川, 昭弥"},{"creatorName":"オガワ, アキヤ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"田中, 宏道"},{"creatorName":"タナカ, ヒロミチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"秋山, 隆彦"},{"creatorName":"アキヤマ, タカヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"福沢, 信一"},{"creatorName":"フクザワ, シンイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-04-22"}],"displaytype":"detail","filename":"1343_0068~7~~37.pdf","filesize":[{"value":"461.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文を見る(PDFファイル)","url":"https://chuo-u.repo.nii.ac.jp/record/1264/files/1343_0068~7~~37.pdf"},"version_id":"6542b59f-bd05-4aa2-84e6-bc3622e2ac99"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"クロロシラン共存下における低原子価サマリウム試薬によるケトン類の還元反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"クロロシラン共存下における低原子価サマリウム試薬によるケトン類の還元反応"},{"subitem_title":"Reduction of Ketones with Low-Valent Samarium Reagents in the　Presence of Chlorosilane","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"1","path":["118"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-10-01"},"publish_date":"2012-10-01","publish_status":"0","recid":"1264","relation_version_is_last":true,"title":["クロロシラン共存下における低原子価サマリウム試薬によるケトン類の還元反応"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-16T13:27:24.167880+00:00"}