@article{oai:chuo-u.repo.nii.ac.jp:00003812, author = {寺島, 貴大 and 猪俣, さゆり and 緒方, 賢一 and 福沢, 信一}, journal = {中央大学理工学研究所論文集}, month = {Mar}, note = {application/pdf, A catalytic efficiency of 1,2,3-triazol-5-ylidene (tzNHC) palladium π-allyl complexes was evaluated in α-arylation of aryl ketones with aryl chlorides. Sterically hindered 1,4-(2,6-diisopropylphenyl-1,2,3-triazol-5-ylidene) was the most suitable tzNHC, and allylic ligands did not much affect the catalytic efficiency. 1,4-(2,6-Diisopropylphenyl¬1,2,3-triazol-5-ylidene) palladium(allyl) complex C3 was able to be applied to the α-arylation with several aryl chlorides. C3 also catalyzed Mizoroki-Heck reaction of aryl bromides with n-butyl acrylate to give the corresponding cinnamic acid esters in good yields.}, pages = {1--7}, title = {1,2,3-トリアゾールイリデンカルベン パラジウム π-アリル 錯体を用いるケトンの直接的α-アリール化反応と溝呂木-Heck 反応}, volume = {18}, year = {2013}, yomi = {テラシマ, マサヒロ and イノマタ, サユリ and オガタ, ケンイチ and フクザワ, シンイチ} }