{"created":"2023-05-15T13:44:53.912979+00:00","id":3812,"links":{},"metadata":{"_buckets":{"deposit":"5caaf470-b9b7-42de-9a43-39c4c8e02883"},"_deposit":{"created_by":1,"id":"3812","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"3812"},"status":"published"},"_oai":{"id":"oai:chuo-u.repo.nii.ac.jp:00003812","sets":["108:257"]},"author_link":["24844","24845","24841","23392","24842","24843"],"item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-03-31","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"7","bibliographicPageStart":"1","bibliographicVolumeNumber":"18","bibliographic_titles":[{"bibliographic_title":"中央大学理工学研究所論文集"}]}]},"item_10002_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10002_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A catalytic efficiency of 1,2,3-triazol-5-ylidene (tzNHC) palladium π-allyl complexes was evaluated in α-arylation of aryl ketones with aryl chlorides. Sterically hindered 1,4-(2,6-diisopropylphenyl-1,2,3-triazol-5-ylidene) was the most suitable tzNHC, and allylic ligands did not much affect the catalytic efficiency. 1,4-(2,6-Diisopropylphenyl¬1,2,3-triazol-5-ylidene) palladium(allyl) complex C3 was able to be applied to the α-arylation with several aryl chlorides. C3 also catalyzed Mizoroki-Heck reaction of aryl bromides with n-butyl acrylate to give the corresponding cinnamic acid esters in good yields.","subitem_description_type":"Abstract"}]},"item_10002_full_name_32":{"attribute_name":"著者別名(英)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"24844","nameIdentifierScheme":"WEKO"}],"names":[{"name":"TERASHIMA, Masahiro","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"24845","nameIdentifierScheme":"WEKO"}],"names":[{"name":"INOMATA, Sayuri","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"24843","nameIdentifierScheme":"WEKO"}],"names":[{"name":"OGATA, Kenichi","nameLang":"en"}]},{"nameIdentifiers":[{"nameIdentifier":"23392","nameIdentifierScheme":"WEKO"}],"names":[{"name":"FUKUZAWA, Shin-ichi","nameLang":"en"}]}]},"item_10002_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24789/00003802","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"中央大学理工学研究所"}]},"item_10002_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"この資料の著作権は、資料の著作者または学校法人中央大学に帰属します。著作権法が定める私的利用・引用を超える使用を希望される場合には、掲載誌発行部局へお問い合わせください。"}]},"item_10002_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1343-0068","subitem_source_identifier_type":"ISSN"}]},"item_10002_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"寺島, 貴大"},{"creatorName":"テラシマ, マサヒロ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"猪俣, さゆり"},{"creatorName":"イノマタ, サユリ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"緒方, 賢一"},{"creatorName":"オガタ, ケンイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"福沢, 信一"},{"creatorName":"フクザワ, シンイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-04-22"}],"displaytype":"detail","filename":"1343_0068~~18~1.pdf","filesize":[{"value":"3.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"本文を見る(PDFファイル)","url":"https://chuo-u.repo.nii.ac.jp/record/3812/files/1343_0068~~18~1.pdf"},"version_id":"8d4db64a-6c76-4e52-8c41-3dd706085ab4"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"1,2,3-トリアゾールイリデンカルベン パラジウム π-アリル 錯体を用いるケトンの直接的α-アリール化反応と溝呂木-Heck 反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"1,2,3-トリアゾールイリデンカルベン パラジウム π-アリル 錯体を用いるケトンの直接的α-アリール化反応と溝呂木-Heck 反応"},{"subitem_title":"Direct  -Arylation of Ketones and Mizoroki-Heck Reaction Catalyzed by 1,2,3-Triazolylidene Carbene Palladium  - Allyl Complexes","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"1","path":["257"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-05-17"},"publish_date":"2013-05-17","publish_status":"0","recid":"3812","relation_version_is_last":true,"title":["1,2,3-トリアゾールイリデンカルベン パラジウム π-アリル 錯体を用いるケトンの直接的α-アリール化反応と溝呂木-Heck 反応"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-05-16T13:30:06.640351+00:00"}