WEKO3
アイテム
Effect of mobile phase composition on retention factor in supercritical fluid chromatography
https://doi.org/10.24789/00012109
https://doi.org/10.24789/0001210973a88d05-8b33-41de-a025-477db3da1646
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
本文を見る (725.4 kB)
|
|
| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2020-06-21 | |||||
| タイトル | ||||||
| タイトル | Effect of mobile phase composition on retention factor in supercritical fluid chromatography | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | supercritical fluid chromatography | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | correlation | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | retention factor | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | modifier | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | enantioselective separation | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| ID登録 | ||||||
| ID登録 | 10.24789/00012109 | |||||
| ID登録タイプ | JaLC | |||||
| 著者 |
Sugihara, Tomohito
× Sugihara, Tomohito× Wakamiya, Shohei× Ono, Yuna× Kong, Chang Yi× Sakabe, Junichi× Funazukuri, Toshitaka |
|||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | In supercritical fluid chromatography with a mixture of carbon dioxide and a modifier as the mobile phase, the relationship between retention factor k and modifier mole fraction x was derived as 1/kmix=xCO2/k0CO2 + xmod/k0mod, where kmix, k0CO2, and k0mod are the retention factors for the mixture solvent, pure CO2 and pure modifier, respectively, and xCO2 and xmod are the mole fractions of CO2 and a modifier, respectively. Since k0CO2 and k0mod are often difficult to determine due to too large of a value for k0CO2 and an invalid value of k0mod for the liquid phase, both values were estimated experimentally from the two retention factors available at the lowest and highest modifier mole fractions at each temperature and pressure. The equation was effective for the retention factors of the R- and S-forms of racemic transstilbene oxide measured in the present study by supercritical fluid chromatography using a modifier such as methanol, ethanol or acetonitrile. Moreover, the equation was also valid for the retention data of various enantioselective separations as well as achiral separations reported in the literature. | |||||
| 書誌情報 |
中央大学理工学研究所論文集 巻 24, p. 37-46, 発行日 2019-03-31 |
|||||
| 出版者 | ||||||
| 出版者 | 中央大学理工学研究所 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 1343-0068 | |||||
| 権利 | ||||||
| 権利情報 | この資料の著作権は、資料の著作者または学校法人中央大学に帰属します。著作権法が定める私的利用・引用を超える使用を希望される場合には、掲載誌発行部局へお問い合わせください。 | |||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
